Do not hijack threads, I moved you to a new conversation.
pythagorean-comma "The internal buffer is only intended to drive the ADC inputs, and is not specified for external loads
Then maybe they should have not labelled it like this in the datasheet:

Well, you say that TI says no. But in practice an opamp with large-enough input impedance should be fine. Not sure what 10k in series would do, considering you should have >> Mohm input impedance in your opamp.
TSV524's input impedance is probably very high (>> Mohm), although the datasheet doesn't specify any value.
IC3 uses GND
We are not planning changes at this stage.
pythagorean-comma Future revisions: in post 10 you mentioned possibly changing the analog input range
That might have been about changing REFIO via JP7, e.g.: when powered via lipo or anything below 4.5V.
In general, I wouldn't overthink this. You want to connect an expression pedal, just connect it between 3.3V and GND and use the reduced range (you still get more than 15-bit precision). It's sampled at 22kHz, so you can filter away any additional noise that may be coming from 3.3V being more noisy than VREF.
Humans rarely read netlists. Please do not post AI-generated questions, because I respond by hand. The schematic is there and it is complete. Ask your AI to bring up all the datasheets, the electronics textbooks and all the relevant forum entries and guess the answer to your questions.